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W. H. Freeman: New York, 1997.
ISBN: 0716730421. $80.00.
Daniel Harris's book Quantitative Chemical
Analysis is one of the 1000-pound gorillas for introductory
analytical chemistry, both because of its dominance in the field and
its size and information content. Students find the writing
informal, interesting, and clear. Faculty like the
completeness of the book and its sound treatment of the subject matter. It contains everything that an introductory analytical
course could possibly want. Daniel Harris's recent book,
Exploring Chemical Analysis, is a tamed version of the 1000-pound
gorilla for nonchemistry majors. Students will find the
same informality, interest, and clarity as in the earlier text but
they will also find the book a comfortable companion. Faculty
will find an abbreviated but excellent treatment of the
subject matter. It contains most of the things that an
introductory nonmajors analytical course should want.
Harris has set clear priorities in developing this
book. He has focused clearly on the most important
fundamentals and topics in the nonmajors course. He has
extensively pruned the less important material but left the
important material, such as acidbase chemistry, largely untouched.
He has eliminated the general treatments, diving directly
into specific topics. Ideas that were foreshadowed in earlier
sections and repeated subsequently are now treated only
once. The book is somewhat more qualitative and uses
pictures more efficiently. Practical tips and experimental details are
sacrificed when they do not relate directly to principles or
common laboratory experiences. Despite the extensive
changes, the book remains well integrated and coherent.
Faculty will find many of their favorite innovations
in the previous text unchanged. The book continues to
make extensive and effective use of margin notes, summaries,
tips, connections to forgotten mathematics,
demonstrations, worked examples, examples from the research literature
and current topics, spreadsheets, concept questions, and
interesting problems that blend easily with the main text flow.
In addition to the regular problems, each chapter has simple problems that the students work as they read the material
so they can better master the ideas. Complete solutions to
these problems are in the back of the book.
And then of course, there are the topics that are left
out. Although each individual will have favorite casualties,
I mourned the loss of a quantitative treatment of
chelation equilibria and oxidationreduction titrations. Chelation
loses its separate chapter and now shares a qualitative chapter
with iodine titrations. It is used to discuss the different
titration strategies such as back-titrations, masking, displacement
titrations, and indirect titrations. Although the earlier
book did have a brief discussion of thermodynamic concepts,
any mention of thermodynamics has been eliminated in this text.
To compensate, Harris has added some very
nice examples. The current text has a number of fresh
examples of analytical applications in environmental and biological
areas. The analytical chemistry of fish tanks has also been
added. There are a number of new experiments that
provide excellent illustrations of the environmental and biological
applications. There are even initial attempts to relate the analytical
chemistry to organic chemistry.
Exploring Chemical
Analysis is likely to find a receptive audience. Because of the severe pruning, the text is
much more focused and manageable by students who may have
discomfort with chemistry. Harris does an excellent job of
making the subject matter clear, concise, and interesting
without removing much of the important chemistry. I would
strongly recommend this textbook for an introductory
nonmajors analytical chemistry course.
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