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  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > February  >
Chemical Education Today
Corrections
Correction to J. Chem. Educ. 1998, 75, 1641-1645
Chien M. Wai, Fred Hunt, Min Ji, and Xiaoyuan Chen
University of Idaho, Department of Chemistry, Moscow, ID 83844-2343

Cover
February 1999
Vol. 76 No. 2
p. 166

Full Text

The article "Chemical Reactions in Supercritical Carbon Dioxide"; (Wai, C. M.; Hunt, F.; Ji, M.; Chen, X. J. Chem. Educ. 1998, 75, 1641-1645) should be corrected as follows:

On page 1641 under the section Hydrogenation and Hydroformylation, the first paragraph should appear as shown below with corrections in boldface.

The work by Jessop et al. was mistakenly cited as by Leitner et al. in the article. We apologize for the mistake.

Hydrogenation and Hydroformylation

High concentrations of CO2 in the supercritical fluid phase can be advantageous for chemical reactions that incorporate CO2. For example, in conventional synthesis, hydrogenation of CO2 to formic acid is rendered thermodynamically favorable by the addition of a base in an organic solvent. This reaction is highly efficient in scCO2 (Scheme I). The hydrogenation of CO2 to formic acid using an organic rhodium catalyst in dimethyl sulphoxide in a pressurized system was investigated by Graf and Leitner (11). Efficient production of formic acid in a supercritical mixture of CO2 and H2, containing a trimethylphosphine complex of RuII as a catalyst precursor, was reported by Jessop et al. (12). The use of a scCO2 phase, in which hydrogen can be dissolved with a much higher concentration, leads to a very high initial rate of reactionup to 1,400 moles of formic acid per mole of catalyst per hour. The rate of the same reaction under identical conditions in liquid organic solvents is lower by an order of magnitude (12).

More Information
*  Citation
Wai, Chien M.; Hunt, Fred; Ji, Min; Chen, Xiaoyuan. J. Chem. Educ. 1999 76 166.
*  Keywords
Organic Synthesis; Inorganic Synthesis; Organometallics; Corrections
*  History
Created:
Last Updated:
June 15, 1999
June 22, 2005
Link to Article added (June 2004).
  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > February



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