TOPIC: 20. Amines / Ammonium Compounds

SUBTOPIC: 201. Arenediazonium Salts

1. Give the major product(s) of the following reaction.

________________________________________________________________________

________________________________________________________________________

2. Give a specific example of the synthesis of an azo dye by writing an equation. Don't use any R groups.

________________________________________________________________________

________________________________________________________________________

3. Give the major product(s) of the following reaction.

________________________________________________________________________

________________________________________________________________________

4. Show the reagents necessary for the following transformation. Number the steps required if the reagents cannot be mixed at the same time. Mark each as an Oxidation, Reduction or Neither.

_______________________________________________________________________

_______________________________________________________________________

5. Show how you would perform the following synthesis. Give all reagents and isolable intermediate products.

________________________________________________________________________

________________________________________________________________________

6. Give the major product of the following reaction.

________________________________________________________________________

________________________________________________________________________

7. Give the starting material(s) used to make the following compound.

________________________________________________________________________

________________________________________________________________________

8. Show how you would accomplish the following synthetic transformation. Show all isolated intermediate compounds along the way.

________________________________________________________________________

________________________________________________________________________

9. Show the mechanism of the following reaction with all intermediates and electron-pushing arrows.

________________________________________________________________________

________________________________________________________________________

10. Give the major product of the following reaction.

________________________________________________________________________

________________________________________________________________________

11. Give the starting material(s) used to make the following compound.

________________________________________________________________________

12. Show how you would accomplish the following synthetic transformation. Show all isolated intermediate compounds along the way.

________________________________________________________________________

________________________________________________________________________