TOPIC: 20. Amines
SUBTOPIC: 205. Synthesis
1. What is the major product of the following reaction?
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2. What is the major product of the following reaction?
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3. Show how you would accomplish the following synthetic transformation. Give all reagents and isolated products.
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4. Show the reagents necessary for the following conversion. Number the steps required if the reagents cannot be mixed at the same time, but do not show intermediate compounds or mechanisms.
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5. Give a specific example of a reaction which involves an isocyanate intermediate by writing an equation. Don’t use any R groups.
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6. Write the complete mechanism of the following reaction. Show all intermediates, electron-pushing arrows and formal charges.
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7. Give the product of the following reaction.
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8. Give the major product(s) of the following reaction.
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9. Show the reagents necessary for the following transformation. Number the steps required if the reagents cannot be mixed at the same time. Mark the reaction as an Oxidation, Reduction or Neither.
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10. Show how you would accomplish the following synthesis. Give all reagents and isolable intermediate products.
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11. Show how you would accomplish the following synthesis. Give all reagents and isolable intermediate products.
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12. Show the reagents necessary for the following transformation. Number the steps required if the reagents cannot be mixed at the same time. Mark the reaction as an Oxidation, Reduction or Neither.
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13. Give a specific example of a reaction which works for the following reagent. Show starting material, reagents over the arrow and product(s). Don't use R groups.
NaN3
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14. Give a specific example of a reaction in which following reagent is used. Show starting material, reagents over the arrow and product(s). Don't use R groups.
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15. Show how you would accomplish the following synthesis. Give all reagents and isolable intermediate products.
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16. Give the major product(s) of the following reaction.
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17. Give the major product(s) of the following reaction.
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18. Give the reagents over the arrow. Number them if they cannot be mixed.
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19. Give the reagents over the arrow. Number them if they cannot be mixed.
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20. Give the major product of the following reaction.
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22. Give the major product of the following reaction.
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23. Give the major product of the following reaction.
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24. Write the complete mechanism of the following reaction. Show all intermediates, electron-pushing arrows and formal charges.
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