Nickel formate is important as a source of finely divided, catalytically active, metal, and is usually prepared either by metathetical reactions between the appropriate nickel salts and metal formates or by crystallizing the aqueous solution obtained by the reaction of formic acid with nickel carbonate, oxide, or hydroxide. The preparation method described here consists of reacting an aqueous solution of nickel acetate with formic acid and has some advantages over the above mentioned methods. It yields a more pure product than the metathetical reactions method. The work up is easier than in the crystallization because the acetate is much more soluble in water than the formate so that the volume of solution to be handled is reduced considerably.
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