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  Home > JCE Print > Journal of Chemical Education > Issues > 1996  > April  >
Features
Textbook Forum
The Boltzmann Distribution
Douglas K. Russell
University of Auckland, Private Bag 92019, Auckland, New Zealand
Cover
April 1996
Vol. 73 No. 4
p. 299
Abstract
It is demonstrated that the Boltzmann Distribution may be derived in a straightforward manner by using a combination of the Boltzmann formula for entropy and the requirement of minimum Helmholtz energy for equilibrium in a closed system of constant volume. This approach avoids the use of unfamiliar mathematical techniques such as Lagrange's Method of Undetermined Multipliers.
More Information
*  Citation
 Russell, Douglas K. J. Chem. Educ. 1996 73 299.
*  Keywords
*  History
 Created:
Last Updated:		 9/23/1999
5/22/2006
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