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  Home > JCE Print > Journal of Chemical Education > Issues > 1997  > December  >
In the Laboratory
Complexometric Titration of Zinc: An Analytical Chemistry Laboratory Experiment
S. G. Novick
Hofstra University, Department of Chemistry, Hempstead, NY 11549-1350

Cover
December 1997
Vol. 74 No. 12
p. 1463

Abstract
Complexometric titrations with EDTA have traditionally been performed in undergraduate analytical chemistry courses to determine the calcium or magnesium content of water. These titrations are performed at a basic pH, where the formation constants of Ca-EDTA and Mg-EDTA complexes are high. These types of problems are well-treated in the analytical chemistry textbooks. In contrast, treatment of metal ions whose EDTA complexes occur significantly at low pH (e.g., Zn2+, Fe3+, Cu2+, Ni2+, Pb2+, Al3+) is sparse. An incorrect conclusion can be reached by the student that practical EDTA titrations are only performed at high pH. In addition, widening the window of possible metal ions for complexometric titration affords the possibility of analyzing real world products, such as the cold lozenges discussed in the article.
More Information
*  Citation
Novick, S. G. J. Chem. Educ. 1997 74 1463.
*  Keywords
Analytical Chemistry, Zinc, Titrimetry, and Laboratory Instruction
*  History
Created:
Last Updated:
July 20, 1999
June 23, 2005
  Home > JCE Print > Journal of Chemical Education > Issues > 1997 > December > Page 1463


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