This article provides information that expands upon and clarifies certain points put forth by Robert Q. Thompson in his article, "The Thermodynamics of Drunk Driving" (J. Chem. Educ.1997, 74, 532-536). I have reservations concerning the limited scope and basis of some of Thompson's conclusions, and offer information consistent with a broader perspective. The principal focus of Thompson's work is on the postabsorptive state of alcohol metabolism. He makes recommendations concerning the application of breath-alcohol analysis to motor vehicle operators arrested for driving under the influence (DUI) of alcohol, assuming they are postabsorptive. I question the validity of a uniform application of this assumption to all DUI arrestees. Arguments are presented to support the position that many DUI arrestees can be in the absorptive state. Under that condition, breath-alcohol analysis can be particularly discriminatory to test subjects, and I have provided data consistent with this conclusion.
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Citation
Labianca, Dominick A. J. Chem. Educ.1999 76 508.
Keywords
Analytical Chemistry; absorptive state; postabsorptive state; blood/breath ratio
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