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  Home > JCE Print > Journal of Chemical Education > Issues > 1999  > February  >
In the Laboratory
Survey of Binary Azeotropes as Physical Chemistry Lab Experiments with Attention to Cost, Safety, and the Environment
Robert J. Glinski, Christopher W. Smith, and Jason B. Cooke
Tennessee Technological University, Department of Chemistry, Cookeville, TN 38505

Cover
February 1999
Vol. 76 No. 2
p. 227

Abstract
A survey is presented of possible binary azeotropic systems suitable for study in an undergraduate physical chemistry laboratory. From a range of sources, a list has been compiled of the most acceptable systems on the basis of health, safety, waste disposal, and practicability concerns. More than 80 systems were reviewed. For comparison purposes, the list was reduced to a table showing 5 high-boiling and 19 low-boiling azeotropes with their exposure limits, approximate costs, and some physical properties of the mixtures. Comments are made about the strengths and weaknesses of the choice of each. The paper should supply the instructor with sufficient data to choose a binary system for study and with literature sources for further information.

See Letter re: this article.

More Information
*  Citation
Glinski, Robert J.; Smith, Christopher W.; Cooke, Jason B. J. Chem. Educ. 1999 76 227.
*  Keywords
Laboratory Instruction; Physical Chemistry; Solutions / Solvents; Phase Transitions / Diagrams
*  History
Created:
Last Updated:
June 15, 1999
June 22, 2005
Link to Letter added (April 2004).
  Home > JCE Print > Journal of Chemical Education > Issues > 1999 > February > Page 227


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