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Chemical Thermodynamics is one of eleven
monographs in a series entitled "Chemistry for the 21st Century",
which have been published under the direction of IUPAC.
The other topics in this series are advanced materials,
medicinal chemistry, catalysis, stereocontrol of organic
synthesis, ultrafast processes in chemistry and photobiology,
molecular electronics, interfacial science, reactivity of solids,
transition metal catalyzed reactions, and the chemistry of future
energy sources. The purpose of this series, according to the
IUPAC, is to publicize to a wide audience the role that chemistry
will play in the 21st century in the continued development
of society and in the protection of the environment.
Chemical Thermodynamics is not a textbook, but a
collection of 27 essays on topics within the field of
thermodynamics written by 45 authors from the
international chemical thermodynamics community. These topics
were chosen to demonstrate the importance of chemical
thermodynamics in current areas of scientific research and
industrial processes of great economic impact, and in providing
basic scientific knowledge in terms of decision making on
future problems such as population growth, environmental
pollution, and environmental change.
The topics chosen include separation technology,
colloids and microemulsions, electrolytes, adsorption
phenomena, nuclear applications, theoretical and quantum chemistry,
polymer science, microgravity, amorphous materials and
glasses, enzyme-catalyzed reactions, biological applications,
medicine, food science, and petroleum chemistry. The general
format of each of the 27 chapters consists of an introduction to
the topic followed by a general development of the
thermodynamic method employed, some applications or
perspectives, and a short list of references. Classical topics such as the
measurement of bond enthalpies and other thermochemical
properties are not included. The individual chapters, with a
few exceptions, are concise and to the point and appear to
have been extensively edited to provide a common writing
style. An undergraduate student with a good course in
chemical thermodynamics should have little difficulty in reading
most of the text.
Initially, when surveying the various
chapters, I was excited to read about the many applications of
chemical thermodynamics to the above listed areas. I enjoyed,
in particular, learning about topics that might not normally
be associated with chemical thermodynamics, such as
environmental pollution, relative stabilities of
hyperthermophilic enzymes, protein folding, and calorimetry on living
organisms. However, upon more thorough examination, it seems
that the monograph, while excellent in scientific content,
serves more as a justification for the field of chemical
thermodynamics and a compilation of thermodynamic applications
in the 20th century than as a discussion of exciting new
applications in emerging technologies and the solving of
societal problems in the 21st century. My other main criticism is
that although the monograph could possibly be used in a
student seminar or readings course format, the lists of references
at the end of the chapters are not extensive and seem to be
dated. For student use, there should be four or five key
references, designated as such, to provide an entry into the
literature. On a more whimsical note, anyone teaching
undergraduate physical chemistry might wish to have a copy of the
book readily available so that when students ask "why do I have
to take chemical thermodynamics, or what good is
chemical thermodynamics anyway?", 27 reasons can be given.
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