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  Home > JCE Print > Journal of Chemical Education > Issues > 2000  > January  >
In the Laboratory
Contact Angle Goniometry as a Tool for Surface Tension Measurements of Solids, Using Zisman Plot Method. A Physical Chemistry Experiment
Konrad G. Kabza, Jason E. Gestwicki, and Jessica L. McGrath
Department of Chemistry, SUNY at Fredonia, Fredonia, NY 14063
Cover
January 2000
Vol. 77 No. 1
p. 63
Abstract
The paper describes a physical chemistry experiment for measurement of surface tension of solids. It includes description of the Zisman-plot method for obtaining the surface tensions of solids as well as a detailed experimental procedure for surface tension measurements using contact angle goniometry. Four surfaces were analyzed and the critical surface tension (gc) for each of them was obtained. Excellent reproducibility was achieved despite measurement of less accurate Young's contact angles. The experiment includes an extensive data analysis section combined with graphical interpretation of the results. It can be included in an undergraduate physical chemistry laboratory sequence on its own or combined with existing experiments pertaining to surface phenomena.
More Information
*  Citation
 Kabza, Konrad G.; Gestwicki, Jason E.; McGrath, Jessica L. J. Chem. Educ. 2000 77 63.
*  Keywords
 Polymer Chemistry; Physical Chemistry; Surface Science; Laboratory Instruction; Laboratory Equipment / Apparatus
*  History
 Created:
Last Updated:		 December 9, 1999
April 15, 2005
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