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  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > August  >
Information, Textbooks, Media, Resources
Featured Molecules
Chocolate: Theobromine and Caffeine
William F. Coleman
Chemistry Department, Wellesley College, Wellesley, MA 02481

Cover
August 2004
Vol. 81 No. 8
p. 1232

Full Text
The featured molecules this month come from "Chocolate: A Marvelous Natural Product of Chemistry" by Ginger Tannenbaum. As discussed in the article, chocolate is a natural food and is a mixture of many chemical compounds—approximately 400 compounds have been identified in chocolate following fermentation and processing. During processing, a liquid called "chocolate liquor" is formed that is composed of about 55% fat, 17% carbohydrate, 11% protein, and most of the remainder is tannins and ash. Depending on its source, it may also contain theobromine, an alkaloid related to caffeine, in quantities ranging from 0.8% to 1.7%. Caffeine is found in lesser quantities. Theobromine and caffeine are both methyl-xanthines. Theobromine is a smooth muscle stimulant, while caffeine is predominately a central nervous system stimulant. When solidified, the liquor forms bitter (unsweetened) cooking or baking chocolate.

Fully manipulable (Chime) versions of these molecules appear below. These and other molecules are available at Only@JCE Online.

Image of molecule.   Image of molecule.

Figure 1. Theobromine molecule. Interactive Chime-based structure (top); static structure graphic (bottom)

Image of molecule.   Image of molecule.

Figure 2. Caffeine molecule. Interactive Chime-based structure (top); static structure graphic (bottom)

More Information
*  Citation
Coleman, William F. J. Chem. Educ. 2004 81 1232.
*  Keywords
Internet / Web-Based Materials; Molecular Modeling / Dynamics; Molecular Properties / Structure
*  History
Created:
Last Updated:
June 17, 2004
August 10, 2004
  Home > JCE Print > Journal of Chemical Education > Issues > 2004  > August  > Page 1232


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