The principle of stoichiometric uniqueness provides a simple algorithm to check whether a simple redox reaction may be uniquely decomposed into half-reactions in a single way. For complex redox reactions the approach permits a complete enumeration of a finite and unique number of ways a redox reaction may be decomposed into half-reactions. Several examples are given.
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Citation
Fishtik, Ilie; Berka, Ladislav H. J. Chem. Educ.2005 82 553.
Keywords
Electrochemistry; Equilibrium; General Chemistry; Redox Reactions; Stoichiometry; Thermodynamics
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