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  Home > JCE Print > Journal of Chemical Education > Issues > 2006  > January  >
In the Classroom
JCE DigiDemos: Tested Demonstrations
Using a CBL Unit, a Temperature Sensor, and a Graphing Calculator To Model the Kinetics of Consecutive First-Order Reactions as Safe In-Class Demonstrations
Deborah A. Moore-Russo
Department of Learning and Instruction, State University of New York at Buffalo, Buffalo, NY 14260-1000

José E. Cortés-Figueroa
Organometallic Chemistry Research Laboratory, University of Puerto Rico, Mayagüez, PR 00681-9019

checked by Michael J. Schuman
Department of Chemistry, East Stroudsburg University, East Stroudsburg, PA 18301-2999

Cover
January 2006
Vol. 83 No. 1
p. 64

Abstract
A Calculator-Based Laboratory (CBL), a graphing calculator, and the cooling and heating (or heating and cooling) of water are used to model the behavior of consecutive (and biphasic) first-order reactions as safe in-class demonstrations. By measuring the temperature (Tb) of water in a beaker after a sealed vial partially filled with water at temperature Tv is submerged in it (TvTb, Tv ≠ ambient temperature or final temperature), plots of temperature versus time that model the kinetics behavior of biphasic reactions can be produced.
Supplement
The temperature of the water in the beaker as a function of time data used in Figures 2 and 3, and for the five-minute experiment are available.
*  Contents Folder JCE2006p0064W containing Table 1.xls, Table 2.xls, and Table 3.xls (Microsoft Excel)
*  Download
JCE2006p0064W.pdf

JCE2006p0064W.zip

More Information
*  Citation
Moore-Russo, Deborah A.; Cortés-Figueroa, José E. J. Chem. Educ. 2006 83 64.
*  Keywords
Calculator-Based Learning; Calorimetry / Thermochemistry; Demonstrations; Kinetics; Physical Chemistry; Quantitative Analysis; Upper-Division Undergraduate
*  History
Created:
Last Updated:
12/1/2005
12/7/2005
  Home > JCE Print > Journal of Chemical Education > Issues > 2006  > January  > Page 64


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