JCE Online Journal of Chemical EducationDivision of Chemical Education, American Chemical SocietyAmerican Chemical Society
 | Subscriptions  | Software Orders  | Support  | Contributors  | Advertisers  | 

JCE Print
   Current Issue
 Previous Issues
 Supplements
 Search JCE Index

JCE Digital Library
   ChemInfo
 DigiDemos
 Featured Molecules
 LivTexts
 LrnCom
 QBank
 SymMath
 WebWare

JCE Software
   Latest Releases
 Software & Video
 Downloads
 Support

Only@JCE Online
   JCE Online Store
 JCE HS CLIC
 JCE Discussion Forums
   Biographical Snapshots
 ChemEd Resource Shelf
 Featured Molecules
 Hal's Picks
 Project Chemlab
 Reviewed WWW Sites
 "Web-Ed" Articles

About JCE
   Features
 Publications
 Operations
 Outreach
 Contact Us


  Home > JCE Print > Journal of Chemical Education > Issues > 2007  > March  >
Research: Science and Education
Pressure–Volume Integral Expressions for Work in Irreversible Processes
Eric A. Gislason
Department of Chemistry, University of Illinois at Chicago, Chicago, IL 60680

Norman C. Craig
Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074
Cover
March 2007
Vol. 84 No. 3
p. 499
Abstract
Different formulations of thermodynamic work w as a pressure–volume integral are examined for a piston moving against a gas in an irreversible process. Proper expressions are obtained using the instantaneous pressure of the gas on the piston as the integrand and also using certain external pressures as the integrand. There are two common yet different ways to define thermodynamic work, and results are obtained for both definitions. In addition, the contribution to w of the atmosphere in such processes is evaluated. An example is given that illustrates the points made in the paper.
More Information
*
Citation
Gislason, Eric A.; Craig, Norman C. J. Chem. Educ. 2007 84 499.
*
Keywords
Calorimetry / Thermochemistry; Graduate Education / Research; Misconceptions / Discrepant Events; Physical Chemistry; Thermodynamics; Upper-Division Undergraduate
*
History
Created:
Last Updated:
2/1/2007
2/2/2007
<< Previous Article Table of Contents Next Article >>
  Home > JCE Print > Journal of Chemical Education > Issues > 2007  > March  > Page 499


Subscriptions
 Subscription Info
 Order Forms

JCE HS CLIC

Our Secondary School editors work hard to distill all the JCE materials to produce a fraction of particular interest to high school teachers. We call it CLIC.
 JCE HS CLIC

Contributions Welcome
JCE welcomes your submission
 Contributors' Corner

Advertisers
In recent years we have worked hard to better match our advertisers with our readers. When shopping for chemistry education materials, visit our advertisers' WWW sites first.
 Recent Advertisers

Be An Ambassador
Take JCE along on your outreach missions. Copies of the Journal, guest access to JCE Online, our publications catalog, and more are available for your participants.
 Outreach with JCE

Comments to
jceonline@chem.wisc.edu		 Copyright © Division of Chemical Education, Inc., American Chemical Society.
All rights reserved.